Assume laser beam through Air then hits water
Refractive index of air +- 1
Use Snell's Law = n1Sinθ1 = n2Sinθ2
n1 = Refractive index of material 1
n2 = Refractive index of material 2
θ1 = Angle of Incidence
θ2 = Angle of Refraction
n1Sinθ1 = n2Sinθ2
1Sinθ1 = 1.33Sin12°
θ1 = Sin^-1(1.33Sin12°)
θ1 = 16.05°